9/8c – CW – Supernatural – Season 8 Premiere. Dean re-emerges from Purgatory, but he isn’t alone. He heads straight for Sam, but the reunion isn’t exactly what he thought it would be. Sam drops everything to join his brother, but leaving the life he had grown to enjoy turns out to be harder than he imagined. Dean and Sam look for Kevin who has managed to escape Crowley’s grasp, but things come to a head quickly when Kevin tells them what it is that Crowley wants.

10/9c – VH1 – Couples Therapy – Season 2 Premiere. The will examine the complicated and often misunderstood world of high-profile relationships. ” Alex McCord & Simon van Kempen, Shayne and Nik Lamas-Richie, Todd “Too Short” Shaw & Monica Payne, Joel “JoJo” & Tashaunda “Tiny” Hailey, and Doug Hutchison & Courtney Stodden will all take a seat on Dr. Jenn Berman’s couch.

10/9c – Bravo – Life After Top Chef – Series Premiere. The show follows Richard Blais in Atlanta, Jen Carroll in Philadelphia, Spike Mendelsohn in D.C., and Fabio Viviani in Los Angeles as they reach milestones in both their personal lives and culinary careers, from opening their own restaurants to expanding franchises and establishing themselves as culinary leaders in the food world.